This occurs when a character is introduced, but is not revealed to be villainous until much later on, many times within the final act of the story.
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- Akasha (Queen of the Damned)
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- Brooke Mathison (Designated Survivor)
- Carla Hastings (Cyclone)
- Chloe (Scream 4)
- Courtney Lane (Law & Order: SVU)
- Cynthia Fields and Edy Cornfield (Dante)
- Danica Harlan (Altered Carbon)
- Debi (The Homecoming Queen's Got a Gun)
- Diana (Storie Viola)
- Dianne Vaughn (Beauty and the Beast)
- Dr. Shizuka Ichijou (Jutaijima)
- Dr. Wharton (Law & Order: SVU)
- Elektra King (The World Is Not Enough)
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- Erica Chan (CSI: Cyber)
- Ethel (Terror Blu)
- Evil Fairy (Beauty and the Beast)
- Flavia Ducasse (Il Marchese)
- Ga'ran Sigatar Khura'in (Ace Attorney)
- GAIL Henchwoman (Giant Gorg)
- Genesis and Bel (Knock Knock)
- Genietta (Storie Viola)
- Grand High Witch (The Witches)
- Hallelujah (Kuusou Kagaku Sekai Gulliver Boy)
- Hel (Kingdom of Gladiators)
- Hillary Stone (Body of Proof)
- Janet (Storie Blu Special)
- Jill Roberts (Scream 4)
- Jimmy (The Mysteries of Laura)
- Joanna (The Commuter)
- Kara (Amos Burke: Secret Agent)
- Kelly Donovon (Hawaii Five-0)
- Lady Van Tassel (Sleepy Hollow)
- Lily Carver (Kiss Me Deadly)
- Lindo (Alien From The Darkness)
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- Maggie Lynch (Honey West)
- Margo Yeager (Sand Trap)
- Millicent Fairbush (Remington Steele)
- Murderous Mother (Crimestoppers)
- Olivia Peterson (Wicked Moms Club)
- Other Mother (Coraline)
- Professor MacDougal (Mighty Max)
- Rhea (Supergirl)
- Rose Armitage (Get Out)
- Ruby (The Family)
- Sally Marnes (Traffik)
- Sarah Newlin (True Blood)
- Stormfront (The Boys)
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- Tattooist (Tattooist)
- The Mother (The Sitter)
- True Holy Mother of Darkness (Ikei Seibo)
- Velrose/Barbara Ouiblert (Sorcerer Hunters)
- Victoria Leeds (Baywatch)
- Violet Summers (Killer Instinct)
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- A-Squad Pink (Power Rangers SPD)
- Abbey Grey (The Secret Saturdays)
- Abbey Lake (Cold Case)
- Abby (The Blind Death)
- Abby Chadway (Diagnosis Murder)
- Abigail Spencer (CSI)
- Abigail, Amanda & Amy (Relic Hunter)
- Adele Bensimon (Bull)
- Adele Botsford (Diagnosis Murder)
- Adele Manning (No Place to Hide)
- Adele Meyerson (Proven Innocent)
- Adnan Salif (Scandal)
- Adrian Forrester (The Crush)
- Adriana Gorgova (NCIS)
- Adrienna Brassiere (Criminal Case)
- Agatha (Two Sentence Horror Stories)
- Agent Fitzgerald (Unnatural History)
- Agent Jackson (Key and Peele)
- Aggie Wilkins (The Scooby Doo Show)
- Agnes Manners (Criminal Case)
- Aileen (Dylan Dog No. 118)
- Aimee Lee (Garage Sale Mystery)
- Aimee Slocum (Law & Order: SVU)
- AJ (Castle)
- Alana Gonzalez (Law & Order: SVU)
- Alana Leon (Matlock)
- Albertina Thenard (Criminal Case)
- Alchemy (Phantasm II)
- Alex (Decoys)
- Alex Reynolds (Tru Calling)
- Alex/Florentine Swann (V.I.P.)
- Alexa Lee (Lucifer)
- Alexandra Combs (Bones)
- Alexandra Schwartz (NCIS: New Orleans)
- Alexandria McConnell (Fear Street)
- Alexis Hall (The Nightmare Room)
- Alexis Hill (Murder, She Wrote)
- Alexis Palmer (Stalker)
- Alexis Ross (The Gallows)
- Alexis Sawyer (A Dangerous Date)
- Ali Weiss (Lethal Weapon)
- Alice (Satanic)
- Alice August (Criminal Case)
- Alice Diamond (Murder, She Wrote)
- Alice Flagg (Honeymoon From Hell)
- Alice Hart (Fear Street)
- Alice Hill (New Tricks)
- Alice May (Scooby-Doo! Mystery Incorporated)
- Alice McLane (The Monster Doll)
- Alice Sands (Rizzoli & Isles)
- Alice Tuppany (JAG)
- Alice Vanderbilt (Rizzoli & Isles)
- Alice Walters (Secret Liaison)
- Alice Westergren (Monk)
- Alicia Gramble (Crossing Jordan)
- Alicia Kegel (The Rookie)
- Alicia Minault (An Aurora Teagarden Mystery)
- Alicia Senna (Rizzoli & Isles)
- Alicia Spencer (American Horror Story: Coven)
- Alisa Santiago (CSI)
- Alison (CSI: Miami)
- Alison Drexell (Fear Street)
- Alison Wynn's Mother (Running for Her Life)
- Allie Banks (Twin Betrayal)
- Allison Carr (Homeland)
- Allison Clark (Monk)
- Allison Cowley (Psych)
- Allison Grady (CSI: Miami)
- Allison Hyde (Castle)
- Allison Scott (CSI: NY)
- Ally Moore (The Closer)
- Alta Von See (Elementary)
- Alternate Sara Lance (Legends of Tomorrow)
- Alwyn Pierce (Unforgettable)
- Alyssa (Nanny Seduction)
- Alyssa (Tru Calling)
- Amanda (Threads)
- Amanda (Who is Simon Miller?)
- Amanda Calaveras (CSI: Miami)
- Amanda Collier (Castle)
- Amanda Debs (Murder, She Wrote)
- Amanda Harris (Blue Bloods)
- Amanda Haynes (CSI)
- Amanda Purnell (The Defenders)
- Amanda Tanner (Scandal)
- Amanda Temple (Unforgettable)
- Amanda Warner (Secrets and Lies)
- Amaya Vayas (Longmire)
- Amber (Dan Vs.)
- Amber (MacGyver)
- Amber Flaire (Bones)
- Amber Middleberry (Castle)
- Amber Patinelli (Castle)
- Ambrosia (Dark Matter)
- Amelia Browne (Murder, She Wrote)
- Amelia Chase (Law & Order: SVU)
- Amiko (Hercules, Prisoner of Evil)
- Amy (68 Kill)
- Amy (Chuck)
- Amy (Warehouse 13)
- Amy (Whiskey Cavalier)
- Amy Alleris (Psych)
- Amy Barrett (Castle)
- Amy Dujardin (Life)
- Amy Dunne (Gone Girl)
- Amy Kemp (Castle)
- Amy Morgan (Castle)
- Amy Robbins (T.J. Hooker)
- Amy Thomas (Unwanted Guest)
- Amy Turner (Psycho Prom Queen)
- Amy Wainwright (Murder, She Wrote)
- Ana Miller (Tomb Raider)
- Andie (Crush)
- Andrea (Beyond Belief: Fact or Fiction)
- Andrea Barnes (Ransom)
- Andrea Beaumont (Batman: Mask of the Phantasm)
- Andrea Brown (Stalker)
- Andrea Dean (Murder, She Wrote)
- Andrea Esser (Hauptstadtrevier)
- Andrea Fleming (Framed For Murder: A Fixer Upper Mystery)
- Andrea Glassen (Windows)
- Andrea Kent (Law & Order: SVU)
- Andrea Kormos (Supernatural)
- Andrea Rivers (Diagnosis Murder)
- Andrea Todd (Matlock)
- Angel Zacharias (The Flash)
- Angela Alvarez (Careful What You Wish For)
- Angela Dillashaw (Minus 1)
- Angela Goodwin (NCIS: New Orleans)
- Angela Gordon (Abbott and Costello Meet the Killer, Boris Karloff)
- Angela Martin (Body of Proof)
- Angela Mason (Supernatural)
- Angela Muir (Who Killed My Husband?)
- Angela Olvera (Castle)
- Angelica Dira (The Finder)
- Angelina Jennings (NCIS)
- Angeline Dilworth (Monk)
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